Barcelona's league clash with Real Madrid has been scheduled for a 5pm (6pm local time) kickoff on October 26.
The La Liga game, which will take place at Camp Nou, will be the first clash of the season between the two favourites for the Spanish title this season.
The Catalan outfit currently top the table having won all eight of their league fixtures this season, while Madrid sit in third spot, five points behind the current champions.
Week 10 in La Liga will also see the Valencian derby take place between Villarreal and Valencia, while Atletico Madrid will host Real Betis in the late start on Sunday evening.