The Spanish Football Federation have revealed that the European champions will face Belgium in a friendly on November 17.
Spain booked their spot at Euro 2016 with a 4-0 win over Luxembourg on Friday, but still have a final qualifier to play against Ukraine on Monday.
With that in mind, La Roja have revealed their plans for the build-up to next summer's tournament and it will include a friendly with Belgium in Brussels next month.
Spain, who have won the last two editions of the European championships, will host Roy Hodgson's England in Alicante four days earlier.