The 27-year-old scored twice during his side's 5-1 defeat of Real Sociedad at the Santiago Bernabeu on Saturday night.
The forward's 101 goals in 92 games have beaten the record of 105 matches previously held by Real Madrid legend Ferenc Puskas.
The former Manchester United player is the Primera Division's joint-top scorer with Barcelona's Lionel Messi on 35 goals.
Restore Data
| Team | P | W | D | L | F | A | GD | PTS | |
| 1 | Barcelona | 13 | 11 | 0 | 2 | 40 | 12 | 28 | 33 |
| 2 | Real Madrid | 12 | 8 | 3 | 1 | 25 | 11 | 14 | 27 |
| 3 | Atletico MadridAtletico | 13 | 7 | 5 | 1 | 19 | 7 | 12 | 26 |
| 4 | Villarreal | 12 | 7 | 3 | 2 | 23 | 19 | 4 | 24 |
| 5 | Osasuna | 13 | 6 | 3 | 4 | 17 | 20 | -3 | 21 |
| 6 | Athletic Bilbao | 13 | 5 | 5 | 3 | 19 | 13 | 6 | 20 |
| 7 | Real BetisBetis | 13 | 5 | 5 | 3 | 14 | 12 | 2 | 20 |
| 8 | Real Sociedad | 13 | 5 | 3 | 5 | 11 | 10 | 1 | 18 |
| 9 | Mallorca | 13 | 5 | 3 | 5 | 10 | 10 | 0 | 18 |
| 10 | GironaGirona | 13 | 5 | 3 | 5 | 16 | 17 | -1 | 18 |
| 11 | Celta Vigo | 13 | 5 | 2 | 6 | 20 | 22 | -2 | 17 |
| 12 | Rayo Vallecano | 12 | 4 | 4 | 4 | 13 | 13 | 0 | 16 |
| 13 | Sevilla | 13 | 4 | 3 | 6 | 12 | 18 | -6 | 15 |
| 14 | Leganes | 13 | 3 | 5 | 5 | 13 | 16 | -3 | 14 |
| 15 | AlavesAlaves | 13 | 4 | 1 | 8 | 14 | 22 | -8 | 13 |
| 16 | Las PalmasLas Palmas | 13 | 3 | 3 | 7 | 16 | 22 | -6 | 12 |
| 17 | Getafe | 13 | 1 | 7 | 5 | 8 | 11 | -3 | 10 |
| 18 | Espanyol | 12 | 3 | 1 | 8 | 11 | 22 | -11 | 10 |
| 19 | Real ValladolidValladolid | 13 | 2 | 3 | 8 | 10 | 25 | -15 | 9 |
| 20 | Valencia | 11 | 1 | 4 | 6 | 8 | 17 | -9 | 7 |
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