It had been reported that the two clubs were in talks regarding a fee for the 27-year-old's services for the last few days.
An agreement has now been reached, with Napoli revealing that Albiol has signed a four-year contract at the Stadio San Paolo.
The centre-back joined Los Blancos from Valencia in 2009, but after his first season at the Bernabeu, he found starting opportunities hard to come by.
Restore Data
| Team | P | W | D | L | F | A | GD | PTS | |
| 1 | Barcelona | 8 | 7 | 0 | 1 | 25 | 9 | 16 | 21 |
| 2 | Real Madrid | 7 | 5 | 2 | 0 | 16 | 5 | 11 | 17 |
| 3 | Atletico MadridAtletico | 7 | 4 | 3 | 0 | 11 | 3 | 8 | 15 |
| 4 | Mallorca | 8 | 4 | 2 | 2 | 8 | 6 | 2 | 14 |
| 5 | Villarreal | 7 | 4 | 2 | 1 | 14 | 14 | 0 | 14 |
| 6 | Osasuna | 8 | 4 | 2 | 2 | 12 | 13 | -1 | 14 |
| 7 | Athletic Bilbao | 7 | 4 | 1 | 2 | 11 | 7 | 4 | 13 |
| 8 | Rayo Vallecano | 8 | 2 | 4 | 2 | 9 | 8 | 1 | 10 |
| 9 | AlavesAlaves | 8 | 3 | 1 | 4 | 11 | 12 | -1 | 10 |
| 10 | Celta Vigo | 7 | 3 | 0 | 4 | 14 | 14 | 0 | 9 |
| 11 | Real BetisBetis | 7 | 2 | 3 | 2 | 7 | 7 | 0 | 9 |
| 12 | Real Sociedad | 8 | 2 | 2 | 4 | 6 | 7 | -1 | 8 |
| 13 | GironaGirona | 7 | 2 | 2 | 3 | 8 | 10 | -2 | 8 |
| 14 | Sevilla | 7 | 2 | 2 | 3 | 7 | 9 | -2 | 8 |
| 15 | Getafe | 8 | 1 | 4 | 3 | 5 | 6 | -1 | 7 |
| 16 | Espanyol | 7 | 2 | 1 | 4 | 7 | 11 | -4 | 7 |
| 17 | Leganes | 8 | 1 | 4 | 3 | 5 | 9 | -4 | 7 |
| 18 | Valencia | 8 | 1 | 2 | 5 | 5 | 13 | -8 | 5 |
| 19 | Real ValladolidValladolid | 8 | 1 | 2 | 5 | 4 | 17 | -13 | 5 |
| 20 | Las PalmasLas Palmas | 7 | 0 | 3 | 4 | 8 | 13 | -5 | 3 |
| > La Liga Full Table | |||||||||
